2012年1月5日星期四

The Detail Definition of Cadmium sulfide

Cadmium sulfide
Cadmium sulfide is the inorganic compound with the formula CdS. Cadmium sulfide is a yellow solid.It occurs in nature with two different crystal structures as the rare minerals greenockite and hawleyite, but is more prevalent as an impurity substituent in the similarly structured zinc ores sphalerite and wurtzite, which are the major economic sources of cadmium. As a compound that is easy to isolate and purify, it is the principal source of cadmium for all commercial applications.
Cadmium sulfide can be prepared by the precipitation from soluble cadmium(II) salts with sulfide ion and this has been used in the past for gravimetric analysis and qualitative inorganic analysis.Cadmium sulfide has, like zinc sulfide, two crystal forms; the more stable hexagonal wurtzite structure (found in the mineral Greenockite) and the cubic zinc blende structure (found in the mineral Hawleyite). In both of these forms the cadmium and sulfur atoms are four coordinate.There is also a high pressure form with the NaCl rock salt structure.CdS and cadmium selenide are used in manufacturing of photoresistors (light dependent resistors) sensitive to visible and near infrared light.CdS is known as cadmium yellow (CI pigment yellow 37). By adding varying amounts of selenium as selenide, it is possible to obtain a range of colors, for example CI pigment orange 20 and CI pigment red 108.
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